Evolution of porewater in a Neogene sedimentary formation in the Horonobe area, Hokkaido, Japan: Modeling of burial diagenesis

Miyakawa, Kazuya; Kashiwaya, Koki*; Komura, Yuto*; Nakata, Kotaro*

Geochemical Journal, 57(5), p.155 - 175, 2023/00

https://doi.org/10.2343/geochemj.GJ23014

In the thick marine sediments, groundwater altered from seawater during the burial diagenesis may exist. Such altered ancient seawater will be called fossil seawater. In such a field, groundwater flow is considered extremely slow because it is not affected by the seepage of meteoric water even after the uplift. During diagenesis, dehydration from silicates causes changes such as a decrease in the salinity of the porewater. However, dehydration reactions alone cannot quantitatively explain water chemistry changes. In this study, we developed an analytical model that considers the dehydration reaction from silicates during the burial process and the upward migration of porewater due to compaction and examined the possible evolution of porewater chemistry. The results showed that the water chemistry, which was strongly influenced by the dehydration reaction from opal-A to quartz and from smectite, was similar to the observations from boring surveys. The results suggest that the fossil seawater formed during the diagenesis may have been preserved since the uplift and strongly supports the slow groundwater flow in the area where the fossil seawater exists.

Study of corrosion and degradation of the objects in the nuclear reactor by microorganisms (Contract research); FY2020 Nuclear Energy Science & Technology and Human Resource Development Project

Collaborative Laboratories for Advanced Decommissioning Science; Keio University*

JAEA-Review 2021-048, 181 Pages, 2022/01

JAEA-Review-2021-048.pdf:14.5MB

The Collaborative Laboratories for Advanced Decommissioning Science (CLADS), Japan Atomic Energy Agency (JAEA), had been conducting the Nuclear Energy Science & Technology and Human Resource Development Project (hereafter referred to "the Project") in FY2020. The Project aims to contribute to solving problems in the nuclear energy field represented by the decommissioning of the Fukushima Daiichi Nuclear Power Station (1F), Tokyo Electric Power Company Holdings, Inc. (TEPCO). For this purpose, intelligence was collected from all over the world, and basic research and human resource development were promoted by closely integrating/collaborating knowledge and experiences in various fields beyond the barrier of conventional organizations and research fields. The sponsor of the Project was moved from the Ministry of Education, Culture, Sports, Science and Technology to JAEA since the newly adopted proposals in FY2018. On this occasion, JAEA constructed a new research system where JAEA-academia collaboration is reinforced and medium-to-long term research/development and human resource development contributing to the decommissioning are stably and consecutively implemented. Among the adopted proposals in FY2019, this report summarizes the research results of the "Study of corrosion and degradation of the objects in the nuclear reactor by microorganisms" conducted in FY2019 and FY2020. Since the final year of this proposal was FY2020, the results for two fiscal years were summarized. The purpose of the study is to obtain knowledge related to microorganisms that will be useful in the decommissioning process of 1F. Therefore, we clarified the current conditions of the microbial community inhabiting the power plant and its premises. Environmental samples were taken from several sites such as, topsoil from the south of the plant site boundary (south of the treated water tanks), seabed soil and its above water near the plant, surface water 3km offshore …

Study of corrosion and degradation of the objects in the nuclear reactor by microorganisms (Contract research); FY2019 Nuclear Energy Science & Technology and Human Resource Development Project

Collaborative Laboratories for Advanced Decommissioning Science; Keio University*

JAEA-Review 2020-047, 63 Pages, 2021/01

JAEA-Review-2020-047.pdf:3.85MB

The Collaborative Laboratories for Advanced Decommissioning Science (CLADS), Japan Atomic Energy Agency (JAEA), had been conducting the Nuclear Energy Science & Technology and Human Resource Development Project (hereafter referred to "the Project") in FY2019. The Project aims to contribute to solving problems in the nuclear energy field represented by the decommissioning of the Fukushima Daiichi Nuclear Power Station, Tokyo Electric Power Company Holdings, Inc. (TEPCO). For this purpose, intelligence was collected from all over the world, and basic research and human resource development were promoted by closely integrating/collaborating knowledge and experiences in various fields beyond the barrier of conventional organizations and research fields. The sponsor of the Project was moved from the Ministry of Education, Culture, Sports, Science and Technology to JAEA since the newly adopted proposals in FY2018. On this occasion, JAEA constructed a new research system where JAEA-academia collaboration is reinforced and medium-to-long term research/development and human resource development contributing to the decommissioning are stably and consecutively implemented. Among the adopted proposals in FY2019, this report summarizes the research results of the "Study of corrosion and degradation of the objects in the nuclear reactor by microorganisms" conducted in FY2019. The purpose of the study is to obtain knowledge related to microorganisms that will be useful in the decommissioning process of the Fukushima Daiichi Nuclear Power Station. For this reason, the current conditions of the microbial community inhabiting the power plant and its premises will be clarified. In the first research year, we obtained environmental samples such as soils from the south of the boundary of the plant, seabed soils near the plant, and surface water 3 km offshore from the plant, and successfully prepared their microbial genomic DNAs.

Development of tailor-made adsorbents for uranium recovery from seawater on the basis of uranyl coordination chemistry (Contract research); FY2019 Nuclear Energy Science & Technology and Human Resource Development Project

Collaborative Laboratories for Advanced Decommissioning Science; Tokyo Institute of Technology*

JAEA-Review 2020-026, 41 Pages, 2020/12

JAEA-Review-2020-026.pdf:3.25MB

The Collaborative Laboratories for Advanced Decommissioning Science (CLADS), Japan Atomic Energy Agency (JAEA), had been conducting the Nuclear Energy Science & Technology and Human Resource Development Project (hereafter referred to "the Project") in FY2019. The Project aims to contribute to solving problems in the nuclear energy field represented by the decommissioning of the Fukushima Daiichi Nuclear Power Station, Tokyo Electric Power Company Holdings, Inc. (TEPCO). For this purpose, intelligence was collected from all over the world, and basic research and human resource development were promoted by closely integrating/collaborating knowledge and experiences in various fields beyond the barrier of conventional organizations and research fields. The sponsor of the Project was moved from the Ministry of Education, Culture, Sports, Science and Technology to JAEA since the newly adopted proposals in FY2018. On this occasion, JAEA constructed a new research system where JAEA-academia collaboration is reinforced and medium-to-long term research/development and human resource development contributing to the decommissioning are stably and consecutively implemented. Among the adopted proposals in FY2019, this report summarizes the research results of the "Development of Tailor-Made Adsorbents for Uranium Recovery from Seawater on the Basis of Uranyl Coordination Chemistry". On the basis of deep understanding on uranyl coordination chemistry, we design molecular structures of pentadentate ligands as functional moieties for uranium adsorption from seawater and study coordination chemistry of uranyl ion with those ligands in order to resolve current problems in uranium recovery technology from seawater and to develop novel selective and efficient adsorbents for this purpose.

Saturated pool nucleate boiling on heat transfer surface with deposited sea salts

Uesawa, Shinichiro; Koizumi, Yasuo; Shibata, Mitsuhiko; Yoshida, Hiroyuki

Journal of Nuclear Engineering and Radiation Science, 3(4), p.041002_1 - 041002_13, 2017/10

https://doi.org/10.1115/1.4036987

Seawater effects on the soundness of spent fuel cladding tube

Motooka, Takafumi; Ueno, Fumiyoshi; Yamamoto, Masahiro

Proceedings of 2016 EFCOG Nuclear & Facility Safety Workshop (Internet), 6 Pages, 2016/09

At the Fukushima Daiichi nuclear accident, seawater was injected into spent fuel pools of Unit 2-4 for the emergency cooling. Seawater might cause localized corrosion of spent fuel cladding. This would lead to leakage of not only fissile materials but also fission products from fuel cladding. The behavior, however, is not understood well. In this paper, the effects of seawater on corrosion behavior and mechanical property of were studied by using a spent fuel cladding from a BWR. We immersed the spent cladding tubes in diluted artificial seawater for 300h at 353 K, and conducted their visual, cross-sectional and strength examinations. As a localized corrosion index, the pitting potentials of specimens fabricated from the cladding were measured as functions of chloride ion concentration ranging from 20 to 2500 ppm. The visual examination showed that localized corrosion has not occurred, and cross-sectional examination showed no cracks. The strength of immersed tubes was comparable to that of non-immersed tubes. Additionally, pitting potential could not be measured over 1.0 V; pitting corrosion was hardly occurred. These results suggested that the specimens from the spent fuel cladding tube was very resistant to localized corrosion.

Pool nucleate boiling on heat transfer surface with deposited sea salts

Uesawa, Shinichiro; Koizumi, Yasuo; Shibata, Mitsuhiko; Yoshida, Hiroyuki

Proceedings of 24th International Conference on Nuclear Engineering (ICONE-24) (DVD-ROM), 15 Pages, 2016/06

https://doi.org/10.1115/ICONE24-60524

Pool nucleate boiling for seawater containing minerals

Uesawa, Shinichiro; Koizumi, Yasuo; Yoshida, Hiroyuki

Proceedings of 9th International Conference on Multiphase Flow (ICMF 2016) (CD-ROM), 6 Pages, 2016/05

Corrosion rate of carbon steel in NaCl solution with various chloride ion concentration under -ray irradiation

Motooka, Takafumi

JAEA-Review 2015-022, JAEA Takasaki Annual Report 2014, P. 23, 2016/02

https://doi.org/10.11484/jaea-review-2015-022

Corrosion rates of carbon steel in chloride aqueous solutions under a low dose rate were investigated by corrosion test using chloride aqueous solutions with different chloride concentrations. The corrosion rate of carbon steel had the maximum value at a certain concentration at a dose rate of 500Gy/h. The oxidants produced by radiolysis of chloride aqueous solution enhanced the corrosion of carbon steel. The dependence of corrosion rate and chloride concentration has a positive correlation with the dependence of oxidant concentration and chloride concentration.

Evaluation of seawater effects on thermal-hydraulic behavior for severe accident conditions, 2; Heat transfer and flow visualization experiment by using internally heated annulus

Uesawa, Shinichiro; Nagatake, Taku; Jiao, L.; Liu, W.; Takase, Kazuyuki; Yoshida, Hiroyuki

Proceedings of International Conference on Power Engineering 2015 (ICOPE 2015) (CD-ROM), 11 Pages, 2015/11